Manganese(II,III) oxide

Manganese(II,III) oxide
Names
IUPAC name
manganese(II) dimanganese(III) oxide
Other names
Manganese tetroxide; Manganese oxide, Manganomanganic oxide, Trimanganese tetraoxide, Trimanganese tetroxide[1]
Identifiers
3D model (JSmol)
ECHA InfoCard 100.013.879 Edit this at Wikidata
RTECS number
  • OP0895000
UNII
  • InChI=1S/3Mn.4O
    Key: GVNFAUMGUISVJW-UHFFFAOYSA-N
  • [Mn]=O.O=[Mn]O[Mn]=O
Properties
Mn3O4

MnO·Mn2O3

Molar mass 228.812 g/mol
Appearance brownish-black powder[1]
Density 4.86 g/cm3
Melting point 1,567 °C (2,853 °F; 1,840 K)
Boiling point 2,847 °C (5,157 °F; 3,120 K)
insoluble
Solubility soluble in HCl
+12,400·10−6 cm3/mol
Structure
Spinel (tetragonal), tI28
I41/amd, No. 141
Hazards
NIOSH (US health exposure limits):
PEL (Permissible)
C 5 mg/m3[1]
REL (Recommended)
None established[1]
IDLH (Immediate danger)
N.D.[1]
Thermochemistry
149 J·mol−1·K−1[2]
−1387 kJ·mol−1[2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Manganese(II,III) oxide is the chemical compound with formula Mn3O4. Manganese is present in two oxidation states +2 and +3 and the formula is sometimes written as MnO·Mn2O3. Mn3O4 is found in nature as the mineral hausmannite.

  1. ^ a b c d e NIOSH Pocket Guide to Chemical Hazards. "#0381". National Institute for Occupational Safety and Health (NIOSH).
  2. ^ a b Zumdahl, Steven S. (2009). Chemical Principles 6th Ed. Houghton Mifflin Company. p. A22. ISBN 978-0-618-94690-7.

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